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In this paper, we successfully synthesized ZnMn₂O₄ nanofibers via simple electrospinning technology followed by calcination process. Only peaks of ZnMn₂O₄ could be observed from X-ray diffractometry patterns, indicating the formation of pure compound. Electrochemical properties of the nanofiber anode material for lithium ion batteries were tested. The as-prepared ZnMn₂O₄ nanofibers exhibited a high initial discharge capacity of 1271.0 mAh g⁻¹, and stabilized capacity was as high as 480.2 mAh g⁻¹ after 30 cycles. The results suggest a promising application of the electrospun ZnMn₂O₄ nanofibers as anode material for lithium ion batteries.